Enhancing Stereocomplexation Ability of Polylactide by Coalescing from Its Inclusion Complex with Urea
نویسندگان
چکیده
In this study, polylactide/urea complexes were successfully prepared by the electrospinning method, then the host urea component was removed to obtain a coalesced poly(L-lactide) (PLLA)/poly(D-lactide) (PDLA) blend. The crystallization behavior of the coalesced PLLA/PDLA blend (c-PLLA/PDLA) was studied by a differential scanning calorimeter (DSC) and Fourier transform infrared (FTIR) spectroscopy. The c-PLLA/PDLA was found to show better crystallization ability than normal PLLA/PDLA blend (r-PLLA/PDLA). More interestingly, the c-PLLA/PDLA effectively and solely crystallized into stereocomplex crystals during the non-isothermal melt-crystallization process, and the reason was attributed to the equally-distributing state of PLLA and PDLA chains in the PLLA/PDLA/urea complex, which led to good interconnection between PLLA and PDLA chains when the urea frameworks were instantly removed.
منابع مشابه
Nano-Stereocomplexation of Polylactide (PLA) Spheres by Spray Droplet Atomization
A direct, efficient, and scalable method to prepare stereocomplexed polylactide (PLA)-based nanoparticles (NPs) is achieved. By an appropriate combination of fabrication parameters, NPs with controlled shape and crystalline morphology are obtained and even pure PLA stereocomplexes (PLASC) are successfully prepared using the spray-drying technology. The formed particles of varying D- and L-LA co...
متن کاملStructural reorganization of cylindrical nanoparticles triggered by polylactide stereocomplexation
Co-crystallization of polymers with different configurations/tacticities provides access to materials with enhanced performance. The stereocomplexation of isotactic poly(L-lactide) and poly(D-lactide) has led to improved properties compared with each homochiral material. Herein, we report the preparation of stereocomplex micelles from a mixture of poly(L-lactide)-b-poly(acrylic acid) and poly(D...
متن کاملPowder metallurgy inspired low-temperature fabrication of high-performance stereocomplexed polylactide products with good optical transparency.
Stereocomplexation between enantiomeric poly(l-lactide) (PLLA) and poly(d-lactide) (PDLA) provides an avenue to greatly enhance performance of eco-friendly polylactide (PLA). Unfortunately, although the manufacturing of semicrystalline polymers generally involves melt processing, it is still hugely challenging to create high-performance stereocomplexed polylactide (sc-PLA) products from melt-pr...
متن کاملReal-time imaging of crystallization in polylactide enantiomeric monolayers at the air-water interface.
A newly developed planar array infrared reflection-absorption spectrograph (PA-IRRAS) offers significant advantages over conventional approaches including fast acquisition speed, excellent compensation for water vapor, and an excellent capacity for large infrared accessories, e.g., a water trough. In this study, the origin of stereocomplexation in a polylactide enantiomeric monolayer at the air...
متن کاملThe role of corn starch, sodium smectite and urea formaldehyde in enhancing the food stability of aquatic organisms
Binders are substances of natural or artificial origin and important in the production of aquatic diets. The binders increase the stability and ability to produce diets and prevent pellets from breaking down in water and during transport. Depending on the raw materials used, the method of making the diet and amount of milling used, the type of aquatic species, and the amount of milling, the typ...
متن کامل